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Reactions of Fluoroalkanes with Mg−Mg Bonds: Scope, sp(3)C−F/sp(2)C−F Coupling and Mechanism
sp(3)C−F Bonds of fluoroalkanes (7 examples; 1°, 2° and 3°) undergo addition to a low‐valent Mg−Mg species generating reactive organomagnesium reagents. Further reactions with a series of electrophiles results in a net C−F to C−B, C−Si, C−Sn or C−C bond transformation (11 examples, diversity). The n...
| Autores principales: | , , , , |
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| Formato: | Online Artículo Texto |
| Lenguaje: | English |
| Publicado: |
John Wiley and Sons Inc.
2018
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| Materias: | |
| Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC6471154/ https://www.ncbi.nlm.nih.gov/pubmed/30207410 http://dx.doi.org/10.1002/chem.201804580 |