Alkynes as Synthetic Equivalents of Ketones and Aldehydes: A Hidden Entry into Carbonyl Chemistry

The high energy packed in alkyne functional group makes alkyne reactions highly thermodynamically favorable and generally irreversible. Furthermore, the presence of two orthogonal π-bonds that can be manipulated separately enables flexible synthetic cascades stemming from alkynes. Behind these “obvi...

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Detalles Bibliográficos
Autores principales: Alabugin, Igor V., Gonzalez-Rodriguez, Edgar, Kawade, Rahul Kisan, Stepanov, Aleksandr A., Vasilevsky, Sergei F.
Formato: Online Artículo Texto
Lenguaje:English
Publicado: MDPI 2019
Materias:
Review
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC6471418/
https://www.ncbi.nlm.nih.gov/pubmed/30875972
http://dx.doi.org/10.3390/molecules24061036

Internet

https://www.ncbi.nlm.nih.gov/pmc/articles/PMC6471418/
https://www.ncbi.nlm.nih.gov/pubmed/30875972
http://dx.doi.org/10.3390/molecules24061036

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