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Highly efficient Ir-catalyzed asymmetric hydrogenation of benzoxazinones and derivatives with a Brønsted acid cocatalyst

The Ir-catalyzed highly efficient asymmetric hydrogenation of benzoxazinones and derivatives was successfully developed with N-methylated ZhaoPhos L5 as the ligand, which may display a new activation mode with a single anion-binding interaction among the substrate, cocatalyst Brønsted acid and ligan...

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Detalles Bibliográficos
Autores principales: Han, Zhengyu, Liu, Gang, Wang, Rui, Dong, Xiu-Qin, Zhang, Xumu
Formato: Online Artículo Texto
Lenguaje:English
Publicado: Royal Society of Chemistry 2019
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC6471538/
https://www.ncbi.nlm.nih.gov/pubmed/31057759
http://dx.doi.org/10.1039/c8sc05797d