Highly selective palladium-catalyzed one-pot, five-fold B–H/C–H cross coupling of monocarboranes with alkenes

Palladium-catalyzed dehydrogenative B–H/C–H cross coupling of monocarborane anions with alkenes is reported, allowing for the first time the isolation of selectively penta-alkenylated boron clusters. The reaction cascade is regioselective for the cage positions, leading directly to B2–6 functionaliz...

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Detalles Bibliográficos
Autores principales: Shen, Yunjun, Zhang, Kang, Liang, Xuewei, Dontha, Rakesh, Duttwyler, Simon
Formato: Online Artículo Texto
Lenguaje:English
Publicado: Royal Society of Chemistry 2019
Materias:
Chemistry
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC6471670/
https://www.ncbi.nlm.nih.gov/pubmed/31057746
http://dx.doi.org/10.1039/c9sc00078j

Internet

https://www.ncbi.nlm.nih.gov/pmc/articles/PMC6471670/
https://www.ncbi.nlm.nih.gov/pubmed/31057746
http://dx.doi.org/10.1039/c9sc00078j

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