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Carbon monoxide insertion at a heavy p-block element: unprecedented formation of a cationic bismuth carbamoyl

Major advances in the chemistry of 5th and 6th row heavy p-block element compounds have recently uncovered intriguing reactivity patterns towards small molecules such as H(2), CO(2), and ethylene. However, well-defined, homogeneous insertion reactions with carbon monoxide, one of the benchmark subst...

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Detalles Bibliográficos
Autores principales: Ramler, Jacqueline, Poater, Jordi, Hirsch, Florian, Ritschel, Benedikt, Fischer, Ingo, Bickelhaupt, F. Matthias, Lichtenberg, Crispin
Formato: Online Artículo Texto
Lenguaje:English
Publicado: Royal Society of Chemistry 2019
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC6471928/
https://www.ncbi.nlm.nih.gov/pubmed/31057745
http://dx.doi.org/10.1039/c9sc00278b