Metal-Dependent Umpolung Reactivity of Carbenes Derived from Cyclopropenes

Metal carbenes, divalent carbon species, are versatile intermediates that enable novel synthetic pathways. These species exhibit either electrophilic or nucleophilic character, depending on the carbene and metal fragments. Although the metal carbene reactivity is regulated by the metal, the umpolung...

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Detalles Bibliográficos
Autores principales: Zhang, Dan, Kang, Zhenghui, Liu, Junwen, Hu, Wenhao
Formato: Online Artículo Texto
Lenguaje:English
Publicado: Elsevier 2019
Materias:
Article
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC6479018/
https://www.ncbi.nlm.nih.gov/pubmed/31015074
http://dx.doi.org/10.1016/j.isci.2019.04.001

Internet

https://www.ncbi.nlm.nih.gov/pmc/articles/PMC6479018/
https://www.ncbi.nlm.nih.gov/pubmed/31015074
http://dx.doi.org/10.1016/j.isci.2019.04.001

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