Cargando…
Metal-Dependent Umpolung Reactivity of Carbenes Derived from Cyclopropenes
Metal carbenes, divalent carbon species, are versatile intermediates that enable novel synthetic pathways. These species exhibit either electrophilic or nucleophilic character, depending on the carbene and metal fragments. Although the metal carbene reactivity is regulated by the metal, the umpolung...
| Autores principales: | , , , |
|---|---|
| Formato: | Online Artículo Texto |
| Lenguaje: | English |
| Publicado: |
Elsevier
2019
|
| Materias: | |
| Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC6479018/ https://www.ncbi.nlm.nih.gov/pubmed/31015074 http://dx.doi.org/10.1016/j.isci.2019.04.001 |