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Origin of the isotropic motion in crystalline molecular rotors with carbazole stators

Herein we report two crystalline molecular rotors 1 and 4 that show extremely narrow signals in deuterium solid-state NMR spectroscopy. Although this line shape is typically associated with fast-moving molecular components, our VT (2)H NMR experiments, along with X-ray diffraction analyses and perio...

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Detalles Bibliográficos
Autores principales: Colin-Molina, Abraham, Jellen, Marcus J., García-Quezada, Eduardo, Cifuentes-Quintal, Miguel Eduardo, Murillo, Fernando, Barroso, Jorge, Pérez-Estrada, Salvador, Toscano, Rubén A., Merino, Gabriel, Rodríguez-Molina, Braulio
Formato: Online Artículo Texto
Lenguaje:English
Publicado: Royal Society of Chemistry 2019
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC6482440/
https://www.ncbi.nlm.nih.gov/pubmed/31057769
http://dx.doi.org/10.1039/c8sc04398a