Conical intersection–regulated intermediates in bimolecular reactions: Insights from C((1)D) + HD dynamics

The importance of conical intersections (CIs) in electronically nonadiabatic processes is well known, but their influence on adiabatic dynamics has been underestimated. Here, through combined experimental and theoretical studies, we show that CIs induce a barrier and regulate conversion from a precu...

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Detalles Bibliográficos
Autores principales: Wu, Yanan, Cao, Jianwei, Ma, Haitao, Zhang, Chunfang, Bian, Wensheng, Nunez-Reyes, Dianailys, Hickson, Kevin M.
Formato: Online Artículo Texto
Lenguaje:English
Publicado: American Association for the Advancement of Science 2019
Materias:
Research Articles
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC6486230/
https://www.ncbi.nlm.nih.gov/pubmed/31032418
http://dx.doi.org/10.1126/sciadv.aaw0446

Internet

https://www.ncbi.nlm.nih.gov/pmc/articles/PMC6486230/
https://www.ncbi.nlm.nih.gov/pubmed/31032418
http://dx.doi.org/10.1126/sciadv.aaw0446

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