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Aromaticity and Antiaromaticity in the Excited States of Porphyrin Nanorings

[Image: see text] Aromaticity can be a useful concept for predicting the behavior of excited states. Here we show that π-conjugated porphyrin nanorings exhibit size-dependent excited-state global aromaticity and antiaromaticity for rings containing up to eight porphyrin subunits, although they have...

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Detalles Bibliográficos
Autores principales: Peeks, Martin D., Gong, Juliane Q., McLoughlin, Kirstie, Kobatake, Takayuki, Haver, Renée, Herz, Laura M., Anderson, Harry L.
Formato: Online Artículo Texto
Lenguaje:English
Publicado: American Chemical Society 2019
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC6488184/
https://www.ncbi.nlm.nih.gov/pubmed/30951313
http://dx.doi.org/10.1021/acs.jpclett.9b00623