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Practical and Scalable Kinetic Resolution of BINOLs Mediated by a Chiral Counterion

BINOLs are valuable and widely used building blocks, chiral ligands, and catalysts that are effective across a remarkable range of different chemical transformations. Here we demonstrate that an ammonium salt catalyzed kinetic resolution of racemic BINOLs with benzyl tosylate proceeds with s up to 4...

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Detalles Bibliográficos
Autores principales: Jones, Benjamin A., Balan, Tudor, Jolliffe, John D., Campbell, Craig D., Smith, Martin D.
Formato: Online Artículo Texto
Lenguaje:English
Publicado: John Wiley and Sons Inc. 2019
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC6492193/
https://www.ncbi.nlm.nih.gov/pubmed/30779415
http://dx.doi.org/10.1002/anie.201814381