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Heterodinuclear zinc and magnesium catalysts for epoxide/CO(2) ring opening copolymerizations

The ring-opening copolymerization of carbon dioxide and epoxides is a useful means to make aliphatic polycarbonates and to add-value to CO(2). Recently, the first heterodinuclear Zn(ii)/Mg(ii) catalyst showed greater activity than either homodinuclear analogue (J. Am. Chem. Soc.2015, 137, 15078–1508...

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Detalles Bibliográficos
Autores principales: Trott, Gemma, Garden, Jennifer A., Williams, Charlotte K.
Formato: Online Artículo Texto
Lenguaje:English
Publicado: Royal Society of Chemistry 2019
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC6492632/
https://www.ncbi.nlm.nih.gov/pubmed/31123572
http://dx.doi.org/10.1039/c9sc00385a