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Rapid unimolecular reaction of stabilized Criegee intermediates and implications for atmospheric chemistry

Elucidating atmospheric oxidation mechanisms is necessary for estimating the lifetimes of atmospheric species and understanding secondary organic aerosol formation and atmospheric oxidation capacity. We report an unexpectedly fast mechanistic pathway for the unimolecular reactions of large stabilize...

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Detalles Bibliográficos
Autores principales: Long, Bo, Bao, Junwei Lucas, Truhlar, Donald G.
Formato: Online Artículo Texto
Lenguaje:English
Publicado: Nature Publishing Group UK 2019
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC6494847/
https://www.ncbi.nlm.nih.gov/pubmed/31043594
http://dx.doi.org/10.1038/s41467-019-09948-7