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Access to P-chiral phosphine oxides by enantioselective allylic alkylation of bisphenols

A novel biscinchona alkaloid-catalyzed highly enantioselective desymmetrization reaction of bisphenol compounds with achiral Morita–Baylis–Hillman carbonate agents was developed. Through the asymmetric allylic alkylation strategy, a broad range of optically active P-stereogenic phosphine oxides were...

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Detalles Bibliográficos
Autores principales: Yang, Guo-Hui, Li, Yao, Li, Xin, Cheng, Jin-Pei
Formato: Online Artículo Texto
Lenguaje:English
Publicado: Royal Society of Chemistry 2019
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC6499109/
https://www.ncbi.nlm.nih.gov/pubmed/31105926
http://dx.doi.org/10.1039/c8sc05439h