Metal–Ligand Cooperation as Key in Formation of Dearomatized Ni(II)–H Pincer Complexes and in Their Reactivity toward CO and CO(2)

[Image: see text] The unique synthesis and reactivity of [((R)PNP*)NiH] complexes (1a,b), based on metal–ligand cooperation (MLC), are presented ((R)PNP* = deprotonated PNP ligand, R = (i)Pr, (t)Bu). Unexpectedly, the dearomatized complexes 1a,b were obtained by reduction of the dicationic complexes...

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Detalles Bibliográficos
Autores principales: Oren, Dror, Diskin-Posner, Yael, Avram, Liat, Feller, Moran, Milstein, David
Formato: Online Artículo Texto
Lenguaje:English
Publicado: American Chemical Society 2018
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC6503609/
https://www.ncbi.nlm.nih.gov/pubmed/31080304
http://dx.doi.org/10.1021/acs.organomet.8b00160

Internet

https://www.ncbi.nlm.nih.gov/pmc/articles/PMC6503609/
https://www.ncbi.nlm.nih.gov/pubmed/31080304
http://dx.doi.org/10.1021/acs.organomet.8b00160

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