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Metal–Ligand Cooperation as Key in Formation of Dearomatized Ni(II)–H Pincer Complexes and in Their Reactivity toward CO and CO(2)
[Image: see text] The unique synthesis and reactivity of [((R)PNP*)NiH] complexes (1a,b), based on metal–ligand cooperation (MLC), are presented ((R)PNP* = deprotonated PNP ligand, R = (i)Pr, (t)Bu). Unexpectedly, the dearomatized complexes 1a,b were obtained by reduction of the dicationic complexes...
| Autores principales: | , , , , |
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| Formato: | Online Artículo Texto |
| Lenguaje: | English |
| Publicado: |
American Chemical
Society
2018
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| Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC6503609/ https://www.ncbi.nlm.nih.gov/pubmed/31080304 http://dx.doi.org/10.1021/acs.organomet.8b00160 |