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Na(+)[Me(3)NB(12)Cl(11)](−)·SO(2): a rare example of a sodium–SO(2) complex

In the title compound, Na(+)[Me(3)NB(12)Cl(11)](−)·SO(2) [systematic name: sodium 1-(trimethylammonio)­undeca­chloro-closo-dodeca­borate sulfur dioxide], the SO(2) mol­ecule is η (1)-O-coordinated to the Na(+) cation. Surprisingly, the SO(2) mol­ecule is more weakly bound to sodium than is found in...

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Detalles Bibliográficos
Autores principales: Jenne, Carsten, van Lessen, Valentin
Formato: Online Artículo Texto
Lenguaje:English
Publicado: International Union of Crystallography 2019
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC6505586/
https://www.ncbi.nlm.nih.gov/pubmed/31110796
http://dx.doi.org/10.1107/S2056989019004663