Crystal structure of penta­carbon­yl(2,2-di­fluoro­propane­thio­ato-κS)manganese(I)

The title compound, [Mn{SC(O)CF(2)CH(3)}(CO)(5)], has been isolated as a by-product during the reaction of K[Mn(CO)(5)] with CH(3)CF(2)COCl. It is built up from a di­fluoro­methyl­propane­thio­ate bonded to an Mn(CO)(5) moiety through the S atom. The Mn atom has an almost perfect octa­hedral coordin...

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Detalles Bibliográficos
Autores principales: Daran, Jean-Claude, Morales-Cerrada, Roberto, Fliedel, Christophe, Gayet, Florence, Ladmiral, Vincent, Ameduri, Bruno, Poli, Rinaldo
Formato: Online Artículo Texto
Lenguaje:English
Publicado: International Union of Crystallography 2019
Materias:
Research Communications
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC6505588/
https://www.ncbi.nlm.nih.gov/pubmed/31110778
http://dx.doi.org/10.1107/S2056989019004134

Internet

https://www.ncbi.nlm.nih.gov/pmc/articles/PMC6505588/
https://www.ncbi.nlm.nih.gov/pubmed/31110778
http://dx.doi.org/10.1107/S2056989019004134

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