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Crystal structure of pentacarbonyl(2,2-difluoropropanethioato-κS)manganese(I)
The title compound, [Mn{SC(O)CF(2)CH(3)}(CO)(5)], has been isolated as a by-product during the reaction of K[Mn(CO)(5)] with CH(3)CF(2)COCl. It is built up from a difluoromethylpropanethioate bonded to an Mn(CO)(5) moiety through the S atom. The Mn atom has an almost perfect octahedral coordin...
| Autores principales: | , , , , , , |
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| Formato: | Online Artículo Texto |
| Lenguaje: | English |
| Publicado: |
International Union of Crystallography
2019
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| Materias: | |
| Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC6505588/ https://www.ncbi.nlm.nih.gov/pubmed/31110778 http://dx.doi.org/10.1107/S2056989019004134 |