Alkali metal complexes of an enantiopure iminophosphonamide ligand with bright delayed fluorescence

The enantiomerically pure ligand P,P-diphenyl-N,N′-bis((R)-1-phenylethyl)phosphinimidic amide (1; (R)-HPEPIA) was synthesized and subsequently deprotonated with alkali metal precursors to yield dimeric complexes [M(2){(R)-PEPIA}(2)] (M = Li (2), Na (3), K (4), Rb (5)). The cesium compound [M{(R)-PEP...

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Detalles Bibliográficos
Autores principales: Feuerstein, Thomas J., Goswami, Bhupendra, Rauthe, Pascal, Köppe, Ralf, Lebedkin, Sergei, Kappes, Manfred M., Roesky, Peter W.
Formato: Online Artículo Texto
Lenguaje:English
Publicado: Royal Society of Chemistry 2019
Materias:
Chemistry
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC6510313/
https://www.ncbi.nlm.nih.gov/pubmed/31160950
http://dx.doi.org/10.1039/c9sc00629j

Internet

https://www.ncbi.nlm.nih.gov/pmc/articles/PMC6510313/
https://www.ncbi.nlm.nih.gov/pubmed/31160950
http://dx.doi.org/10.1039/c9sc00629j

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