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One metal is enough: a nickel complex reduces nitrate anions to nitrogen gas
A stepwise reduction sequence from nitrate to dinitrogen gas at a single nickel center was discovered. A PNP nickel scaffold (PNP(–) = N[2-P(i)Pr(2)-4-Me-C(6)H(3)](2)) emerged as a universal platform for the deoxygenation of NO(x) substrates. In these reactions carbon monoxide acts as the oxygen acc...
| Autores principales: | , , , |
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| Formato: | Online Artículo Texto |
| Lenguaje: | English |
| Publicado: |
Royal Society of Chemistry
2019
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| Materias: | |
| Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC6510316/ https://www.ncbi.nlm.nih.gov/pubmed/31160953 http://dx.doi.org/10.1039/c9sc00717b |