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Synthesis of Ultrahigh Molecular Weight Polymers with Low PDIs by Polymerizations of 1-Decene, 1-Dodecene, and 1-Tetradecene by Cp*TiMe(2)(O-2,6-(i)Pr(2)C(6)H(3))–Borate Catalyst

Polymerizations of 1-decene (DC), 1-dodecene (DD), and 1-tetradecene (TD) by Cp*TiMe(2)(O-2,6-(i)Pr(2)C(6)H(3)) (1)–[Ph(3)C][B(C(6)F(5))(4)] (borate) catalyst have been explored in the presence of Al cocatalyst. The polymerizations of DC and DD, in n-hexane containing a mixture of Al(i)Bu(3) and Al(...

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Detalles Bibliográficos
Autores principales: Nomura, Kotohiro, Pengoubol, Sarntamon, Apisuk, Wannida
Formato: Online Artículo Texto
Lenguaje:English
Publicado: MDPI 2019
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC6515219/
https://www.ncbi.nlm.nih.gov/pubmed/31027258
http://dx.doi.org/10.3390/molecules24081634