Reaction of Nitrogen‐Radicals with Organometallics Under Ni‐Catalysis: N‐Arylations and Amino‐Functionalization Cascades

Herein, we report a strategy for the generation of nitrogen‐radicals by ground‐state single electron transfer with organyl–Ni(I) species. Depending on the philicity of the N‐radical, two types of processes have been developed. In the case of nucleophilic aminyl radicals direct N‐arylation with aryl...

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Detalles Bibliográficos
Autores principales: Angelini, Lucrezia, Davies, Jacob, Simonetti, Marco, Malet Sanz, Laia, Sheikh, Nadeem S., Leonori, Daniele
Formato: Online Artículo Texto
Lenguaje:English
Publicado: John Wiley and Sons Inc. 2019
Materias:
Communications
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC6519068/
https://www.ncbi.nlm.nih.gov/pubmed/30779864
http://dx.doi.org/10.1002/anie.201900510

Internet

https://www.ncbi.nlm.nih.gov/pmc/articles/PMC6519068/
https://www.ncbi.nlm.nih.gov/pubmed/30779864
http://dx.doi.org/10.1002/anie.201900510

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