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Isolation of the Metalated Ylides [Ph(3)P−C−CN]M (M=Li, Na, K): Influence of the Metal Ion on the Structure and Bonding Situation

The isolation and structural characterization of the cyanido‐substituted metalated ylides [Ph(3)P−C−CN]M (1‐M; M=Li, Na, K) are reported with lithium, sodium, and potassium as metal cations. In the solid‐state, most different aggregates could be determined depending on the metal and additional Lewis...

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Detalles Bibliográficos
Autores principales: Schwarz, Christopher, Scharf, Lennart T., Scherpf, Thorsten, Weismann, Julia, Gessner, Viktoria H.
Formato: Online Artículo Texto
Lenguaje:English
Publicado: John Wiley and Sons Inc. 2019
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC6519153/
https://www.ncbi.nlm.nih.gov/pubmed/30556625
http://dx.doi.org/10.1002/chem.201805421