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Rhodium(III) Complexes Featuring Coordinated CF(3) Appendages

The synthesis and characterisation of a homologous series of rhodium 2,2′‐biphenyl complexes featuring intramolecular dative bonding of the nominally inert and weakly coordinating trifluoromethyl group are described. Presence of these interactions is evidenced in the solid state using X‐ray diffract...

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Detalles Bibliográficos
Autores principales: Emerson‐King, Jack, Prokes, Ivan, Chaplin, Adrian B.
Formato: Online Artículo Texto
Lenguaje:English
Publicado: John Wiley and Sons Inc. 2019
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC6519252/
https://www.ncbi.nlm.nih.gov/pubmed/30875135
http://dx.doi.org/10.1002/chem.201901184