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Selective Carbanion–Pyridine Coordination of a Reactive P,N Ligand to Rh(I)
Ligands with reactive carbon sites in the periphery of a metal center have emerged as a powerful approach for metal–ligand bond activation. These reactive carbon sites are commonly generated by deprotonation strategies. Carbon–silicon bond cleavage is a potential alternative to access such construct...
Autores principales: | , , , |
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Formato: | Online Artículo Texto |
Lenguaje: | English |
Publicado: |
John Wiley and Sons Inc.
2019
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Materias: | |
Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC6519283/ https://www.ncbi.nlm.nih.gov/pubmed/30600857 http://dx.doi.org/10.1002/chem.201805504 |