A Redox‐Active Nickel Complex that Acts as an Electron Mediator in Photochemical Giese Reactions

We report a simple protocol for the photochemical Giese addition of C(sp(3))‐centered radicals to a variety of electron‐poor olefins. The chemistry does not require external photoredox catalysts. Instead, it harnesses the excited‐state reactivity of 4‐alkyl‐1,4‐dihydropyridines (4‐alkyl‐DHPs) to gen...

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Detalles Bibliográficos
Autores principales: van Leeuwen, Thomas, Buzzetti, Luca, Perego, Luca Alessandro, Melchiorre, Paolo
Formato: Online Artículo Texto
Lenguaje:English
Publicado: John Wiley and Sons Inc. 2019
Materias:
Communications
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC6519288/
https://www.ncbi.nlm.nih.gov/pubmed/30747467
http://dx.doi.org/10.1002/anie.201814497

Internet

https://www.ncbi.nlm.nih.gov/pmc/articles/PMC6519288/
https://www.ncbi.nlm.nih.gov/pubmed/30747467
http://dx.doi.org/10.1002/anie.201814497

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