Site‐Specific Oxidation State Assignments of the Iron Atoms in the [4Fe:4S](2+/1+/0) States of the Nitrogenase Fe‐Protein

The nitrogenase iron protein (Fe‐protein) contains an unusual [4Fe:4S] iron‐sulphur cluster that is stable in three oxidation states: 2+, 1+, and 0. Here, we use spatially resolved anomalous dispersion (SpReAD) refinement to determine oxidation assignments for the individual irons for each state. Ad...

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Detalles Bibliográficos
Autores principales: Wenke, Belinda B., Spatzal, Thomas, Rees, Douglas C.
Formato: Online Artículo Texto
Lenguaje:English
Publicado: John Wiley and Sons Inc. 2019
Materias:
Communications
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC6519357/
https://www.ncbi.nlm.nih.gov/pubmed/30698901
http://dx.doi.org/10.1002/anie.201813966

Internet

https://www.ncbi.nlm.nih.gov/pmc/articles/PMC6519357/
https://www.ncbi.nlm.nih.gov/pubmed/30698901
http://dx.doi.org/10.1002/anie.201813966

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