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Controllable Isomerization of Alkenes by Dual Visible‐Light‐Cobalt Catalysis

We report herein that thermodynamic and kinetic isomerization of alkenes can be accomplished by the combination of visible light with Co catalysis. Utilizing Xantphos as the ligand, the most stable isomers are obtained, while isomerizing terminal alkenes over one position can be selectively controll...

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Detalles Bibliográficos
Autores principales: Meng, Qing‐Yuan, Schirmer, Tobias E., Katou, Kousuke, König, Burkhard
Formato: Online Artículo Texto
Lenguaje:English
Publicado: John Wiley and Sons Inc. 2019
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC6519376/
https://www.ncbi.nlm.nih.gov/pubmed/30835931
http://dx.doi.org/10.1002/anie.201900849