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Controllable Isomerization of Alkenes by Dual Visible‐Light‐Cobalt Catalysis
We report herein that thermodynamic and kinetic isomerization of alkenes can be accomplished by the combination of visible light with Co catalysis. Utilizing Xantphos as the ligand, the most stable isomers are obtained, while isomerizing terminal alkenes over one position can be selectively controll...
Autores principales: | Meng, Qing‐Yuan, Schirmer, Tobias E., Katou, Kousuke, König, Burkhard |
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Formato: | Online Artículo Texto |
Lenguaje: | English |
Publicado: |
John Wiley and Sons Inc.
2019
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Materias: | |
Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC6519376/ https://www.ncbi.nlm.nih.gov/pubmed/30835931 http://dx.doi.org/10.1002/anie.201900849 |
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