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Breaking Trade‐Off between Selectivity and Activity of Nickel‐Based Hydrogenation Catalysts by Tuning Both Steric Effect and d‐Band Center

For selective hydrogenation of chemicals the high selectivity is always at the expense of activity and improving both selectivity and activity is challenging. Here, by chelating with p‐fluorothiophenol (SPhF)‐arrays, both steric and electronic effects are created to boost the performance of cheap ni...

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Detalles Bibliográficos
Autores principales: Gao, Ruijie, Pan, Lun, Wang, Huiwen, Yao, Yunduo, Zhang, Xiangwen, Wang, Li, Zou, Ji‐Jun
Formato: Online Artículo Texto
Lenguaje:English
Publicado: John Wiley and Sons Inc. 2019
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC6523378/
https://www.ncbi.nlm.nih.gov/pubmed/31131202
http://dx.doi.org/10.1002/advs.201900054