Group 4 Metal and Lanthanide Complexes in the Oxidation State +3 with Tris(trimethylsilyl)silyl Ligands

[Image: see text] A number of paramagnetic silylated d(1) group 4 metallates were prepared by reaction of potassium tris(trimethylsilyl)silanide with group 4 metallates of the type K[Cp(2)MCl(2)] (M = Ti, Zr, Hf). The outcomes of the reactions differ for all three metals. While for the hafnium case...

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Detalles Bibliográficos
Autores principales: Zitz, Rainer, Hlina, Johann, Arp, Henning, Kinschel, Dominik, Marschner, Christoph, Baumgartner, Judith
Formato: Online Artículo Texto
Lenguaje:English
Publicado: American Chemical Society 2019
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC6534343/
https://www.ncbi.nlm.nih.gov/pubmed/31066552
http://dx.doi.org/10.1021/acs.inorgchem.9b00866

Internet

https://www.ncbi.nlm.nih.gov/pmc/articles/PMC6534343/
https://www.ncbi.nlm.nih.gov/pubmed/31066552
http://dx.doi.org/10.1021/acs.inorgchem.9b00866

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