Steric Switching From Photochemical to Thermal N(2) Splitting: A Computational Analysis of the Isomerization Reaction {(Cp(*))(Am)Mo}(2)(μ-η(1):η(1)-N(2)) → {(Cp(*))(Am)Mo}(2)(μ-N)(2)

A μ-η(1):η(1)-N(2)-bridged Mo dimer, {(η(5)-C(5)Me(5))[N(Et)C(Ph)N(Et)]Mo}(2)(μ-N(2)), cleaves dinitrogen thermally resulting in a crystallographically characterized bis-μ-N-bridged dimer, {(η(5)-C(5)Me(5))[N(Et)C(Ph)N(Et)]Mo}(2)(μ-N)(2). A structurally related Mo dimer with a bulkier amidinate liga...

Descripción completa

Detalles Bibliográficos
Autor principal: Krewald, Vera
Formato: Online Artículo Texto
Lenguaje:English
Publicado: Frontiers Media S.A. 2019
Materias:
Chemistry
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC6535493/
https://www.ncbi.nlm.nih.gov/pubmed/31165063
http://dx.doi.org/10.3389/fchem.2019.00352

Internet

https://www.ncbi.nlm.nih.gov/pmc/articles/PMC6535493/
https://www.ncbi.nlm.nih.gov/pubmed/31165063
http://dx.doi.org/10.3389/fchem.2019.00352

Ejemplares similares