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Steric Switching From Photochemical to Thermal N(2) Splitting: A Computational Analysis of the Isomerization Reaction {(Cp())(Am)Mo}(2)(μ-η(1):η(1)-N(2)) → {(Cp())(Am)Mo}(2)(μ-N)(2)

A μ-η(1):η(1)-N(2)-bridged Mo dimer, {(η(5)-C(5)Me(5))[N(Et)C(Ph)N(Et)]Mo}(2)(μ-N(2)), cleaves dinitrogen thermally resulting in a crystallographically characterized bis-μ-N-bridged dimer, {(η(5)-C(5)Me(5))[N(Et)C(Ph)N(Et)]Mo}(2)(μ-N)(2). A structurally related Mo dimer with a bulkier amidinate liga...

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Detalles Bibliográficos
Autor principal:	Krewald, Vera
Formato:	Online Artículo Texto
Lenguaje:	English
Publicado:	Frontiers Media S.A. 2019
Materias:	Chemistry
Acceso en línea:	https://www.ncbi.nlm.nih.gov/pmc/articles/PMC6535493/ https://www.ncbi.nlm.nih.gov/pubmed/31165063 http://dx.doi.org/10.3389/fchem.2019.00352

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