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Defining the S(N)1 Side of Glycosylation Reactions: Stereoselectivity of Glycopyranosyl Cations

[Image: see text] The broad application of well-defined synthetic oligosaccharides in glycobiology and glycobiotechnology is largely hampered by the lack of sufficient amounts of synthetic carbohydrate specimens. Insufficient knowledge of the glycosylation reaction mechanism thwarts the routine asse...

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Detalles Bibliográficos
Autores principales: Hansen, Thomas, Lebedel, Ludivine, Remmerswaal, Wouter A., van der Vorm, Stefan, Wander, Dennis P. A., Somers, Mark, Overkleeft, Herman S., Filippov, Dmitri V., Désiré, Jérôme, Mingot, Agnès, Bleriot, Yves, van der Marel, Gijsbert A., Thibaudeau, Sebastien, Codée, Jeroen D. C.
Formato: Online Artículo Texto
Lenguaje:English
Publicado: American Chemical Society 2019
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC6535769/
https://www.ncbi.nlm.nih.gov/pubmed/31139714
http://dx.doi.org/10.1021/acscentsci.9b00042