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Reversible Control of the Mn Oxidation State in SrTiO(3) Bulk Powders

We demonstrate a low-temperature reduction method for exhibiting fine control over the oxidation state of substitutional Mn ions in strontium titanate (SrTiO(3)) bulk powder. We employ NaBH(4) as the chemical reductant that causes significant changes in the oxidation state and oxygen vacancy complex...

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Detalles Bibliográficos
Autores principales: Mansoor, Haneen, Harrigan, William L., Lehuta, Keith A., Kittilstved, Kevin R.
Formato: Online Artículo Texto
Lenguaje:English
Publicado: Frontiers Media S.A. 2019
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC6538879/
https://www.ncbi.nlm.nih.gov/pubmed/31179268
http://dx.doi.org/10.3389/fchem.2019.00353