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Catalytic reduction of aryl trialkylammonium salts to aryl silanes and arenes

A new approach for the reduction of aryl ammonium salts to arenes or aryl silanes using nickel catalysis is reported. This method displays excellent ligand-controlled selectivity based on the N-heterocyclic carbene (NHC) ligand employed. Utilizing a large NHC in non-polar solvents generates aryl sil...

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Detalles Bibliográficos
Autores principales: Rand, Alexander W., Montgomery, John
Formato: Online Artículo Texto
Lenguaje:English
Publicado: Royal Society of Chemistry 2019
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC6540906/
https://www.ncbi.nlm.nih.gov/pubmed/31191891
http://dx.doi.org/10.1039/c9sc01083a