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Au-catalyzed skeletal rearrangement of O-propargylic oximes via N–O bond cleavage with the aid of a Brønsted base cocatalyst
O-Propargylic oximes that possess an electron-withdrawing aryl group on the oxime moiety undergo Au-catalyzed skeletal rearrangements via N–O bond cleavage to afford the corresponding 2H-1,3-oxazine derivatives. Our studies show that the inclusion of a Brønsted base cocatalyst not only accelerates t...
| Autores principales: | , , , |
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| Formato: | Online Artículo Texto |
| Lenguaje: | English |
| Publicado: |
Royal Society of Chemistry
2019
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| Materias: | |
| Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC6540908/ https://www.ncbi.nlm.nih.gov/pubmed/31191884 http://dx.doi.org/10.1039/c9sc00501c |