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Brønsted acid catalysis – the effect of 3,3′-substituents on the structural space and the stabilization of imine/phosphoric acid complexes
BINOL derived chiral phosphoric acids (CPAs) are widely known for their high selectivity. Numerous 3,3′-substituents are used for a variety of stereoselective reactions and theoretical models of their effects are provided. However, experimental data about the structural space of CPA complexes in sol...
Autores principales: | , , , , |
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Formato: | Online Artículo Texto |
Lenguaje: | English |
Publicado: |
Royal Society of Chemistry
2019
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Materias: | |
Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC6540909/ https://www.ncbi.nlm.nih.gov/pubmed/31191877 http://dx.doi.org/10.1039/c9sc01044k |