Cargando…
Using coligands to gain mechanistic insight into iridium complexes hyperpolarized with para-hydrogen
We report the formation of a series of novel [Ir(H)(2)(IMes)(α-(13)C(2)-carboxyimine)L] complexes in which the identity of the coligand L is varied. When examined with para-hydrogen, complexes in which L is benzylamine or phenethylamine show significant (1)H hydride and (13)C(2) imine enhancements a...
| Autores principales: | , , , , , |
|---|---|
| Formato: | Online Artículo Texto |
| Lenguaje: | English |
| Publicado: |
Royal Society of Chemistry
2019
|
| Materias: | |
| Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC6540910/ https://www.ncbi.nlm.nih.gov/pubmed/31191878 http://dx.doi.org/10.1039/c9sc00444k |