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Using coligands to gain mechanistic insight into iridium complexes hyperpolarized with para-hydrogen

We report the formation of a series of novel [Ir(H)(2)(IMes)(α-(13)C(2)-carboxyimine)L] complexes in which the identity of the coligand L is varied. When examined with para-hydrogen, complexes in which L is benzylamine or phenethylamine show significant (1)H hydride and (13)C(2) imine enhancements a...

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Detalles Bibliográficos
Autores principales:	Tickner, Ben. J., John, Richard O., Roy, Soumya S., Hart, Sam J., Whitwood, Adrian C., Duckett, Simon B.
Formato:	Online Artículo Texto
Lenguaje:	English
Publicado:	Royal Society of Chemistry 2019
Materias:	Chemistry
Acceso en línea:	https://www.ncbi.nlm.nih.gov/pmc/articles/PMC6540910/ https://www.ncbi.nlm.nih.gov/pubmed/31191878 http://dx.doi.org/10.1039/c9sc00444k

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