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Ionic liquid cations as methylation agent for extremely weak chalcogenido metalate nucleophiles

Selective in situ methylation of terminal chalcogenide ligands of molecular chalcogenido metalate anions in ionothermal reactions with alkylimidazolium-based ionic liquids yields a series of organo-functionalized chalcogenido metalate compounds. We present the syntheses and crystal structures of (C(...

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Detalles Bibliográficos
Autores principales: Peters, Bertram, Santner, Silke, Donsbach, Carsten, Vöpel, Pascal, Smarsly, Bernd, Dehnen, Stefanie
Formato: Online Artículo Texto
Lenguaje:English
Publicado: Royal Society of Chemistry 2019
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC6540918/
https://www.ncbi.nlm.nih.gov/pubmed/31191876
http://dx.doi.org/10.1039/c9sc01358j