Cargando…

Ionic liquid cations as methylation agent for extremely weak chalcogenido metalate nucleophiles

Selective in situ methylation of terminal chalcogenide ligands of molecular chalcogenido metalate anions in ionothermal reactions with alkylimidazolium-based ionic liquids yields a series of organo-functionalized chalcogenido metalate compounds. We present the syntheses and crystal structures of (C(...

Descripción completa

Detalles Bibliográficos
Autores principales:	Peters, Bertram, Santner, Silke, Donsbach, Carsten, Vöpel, Pascal, Smarsly, Bernd, Dehnen, Stefanie
Formato:	Online Artículo Texto
Lenguaje:	English
Publicado:	Royal Society of Chemistry 2019
Materias:	Chemistry
Acceso en línea:	https://www.ncbi.nlm.nih.gov/pmc/articles/PMC6540918/ https://www.ncbi.nlm.nih.gov/pubmed/31191876 http://dx.doi.org/10.1039/c9sc01358j

Ejemplares similares

Structural Expansion of Chalcogenido Tetrelates in Ionic Liquids by Incorporation of Sulfido Antimonate Units
por: Peters, Bertram, et al.
Publicado: (2020)

Highly Soluble Supertetrahedra upon Selective Partial Butylation of Chalcogenido Metalate Clusters in Ionic Liquids
por: Peters, Bertram, et al.
Publicado: (2021)

Hydrophilic Ionic Liquid Mixtures of Weakly and Strongly Coordinating Anions with and without Water
por: Macchieraldo, Roberto, et al.
Publicado: (2018)

Ionic Liquid‐Driven Formation of and Cation Exchange in Layered Sulfido Stannates – a CH(2) Group Makes the Difference
por: Peters, Bertram, et al.
Publicado: (2020)

Reactions of noble-metal oxides in ionic liquids near room temperature
por: Liebertseder, Mareike, et al.
Publicado: (2023)

Ionic Liquids Catalysis for Carbon Dioxide Conversion With Nucleophiles
por: Xia, Shu-Mei, et al.
Publicado: (2018)

Ionic Liquids as Organocatalysts for Nucleophilic Fluorination: Concepts and Perspectives
por: Oh, Young-Ho, et al.
Publicado: (2022)

Solvolyses of Benzoyl Chlorides in Weakly Nucleophilic Media
por: Bentley, Thomas William, et al.
Publicado: (2011)

Synthesis of Ti(OH)OF ⋅ 0.66 H(2)O in Imidazolium‐based Ionic Liquids
por: Sieland, Melanie, et al.
Publicado: (2020)

Harnessing Ionic Interactions and Hydrogen Bonding for Nucleophilic Fluorination
por: Oh, Young-Ho, et al.
Publicado: (2020)

TiCl(4) Dissolved in Ionic Liquid Mixtures from Аb Initio Molecular Dynamics Simulations
por: Esser, Lars, et al.
Publicado: (2020)

Surface-active ionic liquids in micellar catalysis: impact of anion selection on reaction rates in nucleophilic substitutions
por: Cognigni, Alice, et al.
Publicado: (2016)

Poly Caprolactam Supported Hexaethylene Glycolic Imidazolium Ionic Liquid as a Heterogeneous Promoter for Nucleophilic Fluorination
por: Reddy, Mudumala Veeranarayana, et al.
Publicado: (2023)

Ionic Liquid-Based Low-Temperature Synthesis of Crystalline Ti(OH)OF·0.66H(2)O: Elucidating the Molecular Reaction Steps by NMR Spectroscopy and Theoretical Studies
por: Sieland, Melanie, et al.
Publicado: (2022)

Nucleophilic Substitution in Solution: Activation Strain Analysis of Weak and Strong Solvent Effects
por: Hamlin, Trevor A., et al.
Publicado: (2018)

Cationic clustering influences the phase behaviour of ionic liquids
por: Niemann, Thomas, et al.
Publicado: (2018)

Synthesis of Metal Nanoparticles and Metal Fluoride Nanoparticles from Metal Amidinate Precursors in 1‐Butyl‐3‐Methylimidazolium Ionic Liquids and Propylene Carbonate
por: Schütte, Kai, et al.
Publicado: (2016)

Pathways of ion–molecular interactions of nucleogenic phenyl cations with the nucleophilic centers of picolines
por: Shchepina, Nadezhda E, et al.
Publicado: (2012)

Corrigendum: Synthesis of Metal Nanoparticles and Metal Fluoride Nanoparticles from Metal Amidinate Precursors in 1‐Butyl‐3‐Methylimidazolium Ionic Liquids and Propylene Carbonate
por: Schütte, Kai, et al.
Publicado: (2017)

Amino-polystyrene supported hexaethylene glycol-bridged ionic liquid as an efficient heterogeneous catalyst for water-mediated nucleophilic hydroxylation
por: Reddy, Mudumala Veeranarayana, et al.
Publicado: (2019)

Significant Cation Effects in Carbon Dioxide–Ionic Liquid Systems
por: Hollóczki, Oldamur, et al.
Publicado: (2013)

Rechargeable aluminum batteries: effects of cations in ionic liquid electrolytes
por: Zhu, Guanzhou, et al.
Publicado: (2019)

Pseudohalogen Chemistry in Ionic Liquids with Non‐innocent Cations and Anions
por: Arlt, Sören, et al.
Publicado: (2020)

Metal Assisted Synthesis of Cationic Sulfidobismuth Cubanes in Ionic Liquids
por: Knies, Maximilian, et al.
Publicado: (2020)

Relative Cation-Anion Diffusion in Alkyltriethylammonium-Based Ionic Liquids
por: Kruk, Danuta, et al.
Publicado: (2022)

Coexistence of Tellurium Cations and Anions in Phosphonium‐Based Ionic Liquids
por: Grasser, Matthias A., et al.
Publicado: (2021)

Synthesis of rare-earth metal and rare-earth metal-fluoride nanoparticles in ionic liquids and propylene carbonate
por: Siebels, Marvin, et al.
Publicado: (2018)

Effect of Aromaticity in Anion on the Cation–Anion Interactions and Ionic Mobility in Fluorine-Free Ionic Liquids
por: Khan, Inayat Ali, et al.
Publicado: (2020)

Cation-cation clusters in ionic liquids: Cooperative hydrogen bonding overcomes like-charge repulsion
por: Knorr, Anne, et al.
Publicado: (2015)

Bioinspired Nucleophilic Attack on a Tungsten-Bound Acetylene: Formation of Cationic Carbyne and Alkenyl Complexes
por: Ehweiner, Madeleine A., et al.
Publicado: (2021)

Explaining Ionic Liquid Water Solubility in Terms of Cation and Anion Hydrophobicity
por: Ranke, Johannes, et al.
Publicado: (2009)

Mutual Lewis Acid–Base Interactions of Cations and Anions in Ionic Liquids
por: Holzweber, Markus, et al.
Publicado: (2013)

Influence of Anion and Cation Structure of Ionic Liquids on Carboxylic Acids Extraction
por: Marták, Ján, et al.
Publicado: (2019)

Fluoride Ionic Liquids in Salts of Ethylmethylimidazolium and Substituted Cyclopropenium Cation Families
por: Curnow, Owen J., et al.
Publicado: (2018)

Acyclovir as an Ionic Liquid Cation or Anion Can Improve Aqueous Solubility
por: Shamshina, Julia L., et al.
Publicado: (2017)

Unravelling free volume in branched-cation ionic liquids based on silicon
por: Bakis, Eduards, et al.
Publicado: (2022)

Controlled Cationic Polymerization of p-Methylstyrene in Ionic Liquid and Its Mechanism
por: Zhang, Xiaoqian, et al.
Publicado: (2022)

A Specific Interaction between Ionic Liquids’ Cations and Reichardt’s Dye
por: Mero, Angelica, et al.
Publicado: (2022)

Chalcogenido‐Dimethylgallates and ‐Indates DMPyr(2)[Me(2)M(μ(2)−E)](2) (M=Ga, In; E=S, Se): Building Blocks for Higher and Lower Order Chalcogenidoindates
por: Guschlbauer, Jannick, et al.
Publicado: (2021)

Nucleophilic Isocyanation
por: Yurino, Taiga, et al.
Publicado: (2020)

Cannot write session to /tmp/vufind_sessions/sess_2bfcb79iafjthieg4s6p20mcbj