Stereoselective Ring-Opening (Co)polymerization of β-Butyrolactone and ε-Decalactone Using an Yttrium Bis(phenolate) Catalytic System

An effective route for ring-opening copolymerization of β-butyrolactone (BBL) with ε-decalactone (ε-DL) is reported. Microstructures of the block copolymers characterized by (13)C NMR spectroscopy revealed syndiotactic-enriched poly(3-hydroxybutyrate) (PHB) blocks. Several di- and triblock copolymer...

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Detalles Bibliográficos
Autores principales: Kiriratnikom, Jiraya, Robert, Carine, Guérineau, Vincent, Venditto, Vincenzo, Thomas, Christophe M.
Formato: Online Artículo Texto
Lenguaje:English
Publicado: Frontiers Media S.A. 2019
Materias:
Chemistry
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC6541034/
https://www.ncbi.nlm.nih.gov/pubmed/31192185
http://dx.doi.org/10.3389/fchem.2019.00301

Internet

https://www.ncbi.nlm.nih.gov/pmc/articles/PMC6541034/
https://www.ncbi.nlm.nih.gov/pubmed/31192185
http://dx.doi.org/10.3389/fchem.2019.00301

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