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Stereoselective Ring-Opening (Co)polymerization of β-Butyrolactone and ε-Decalactone Using an Yttrium Bis(phenolate) Catalytic System
An effective route for ring-opening copolymerization of β-butyrolactone (BBL) with ε-decalactone (ε-DL) is reported. Microstructures of the block copolymers characterized by (13)C NMR spectroscopy revealed syndiotactic-enriched poly(3-hydroxybutyrate) (PHB) blocks. Several di- and triblock copolymer...
Autores principales: | Kiriratnikom, Jiraya, Robert, Carine, Guérineau, Vincent, Venditto, Vincenzo, Thomas, Christophe M. |
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Formato: | Online Artículo Texto |
Lenguaje: | English |
Publicado: |
Frontiers Media S.A.
2019
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Materias: | |
Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC6541034/ https://www.ncbi.nlm.nih.gov/pubmed/31192185 http://dx.doi.org/10.3389/fchem.2019.00301 |
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