Strong and Confined Acids Enable a Catalytic Asymmetric Nazarov Cyclization of Simple Divinyl Ketones

[Image: see text] We report a catalytic asymmetric Nazarov cyclization of simple, acylic, alkyl-substituted divinyl ketones using our recently disclosed strong and confined imidodiphosphorimidate Brønsted acids. The corresponding monocyclic cyclopentenones are formed in good yields and excellent reg...

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Detalles Bibliográficos
Autores principales: Ouyang, Jie, Kennemur, Jennifer L., De, Chandra Kanta, Farès, Christophe, List, Benjamin
Formato: Online Artículo Texto
Lenguaje:English
Publicado: American Chemical Society 2019
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC6541325/
https://www.ncbi.nlm.nih.gov/pubmed/30768254
http://dx.doi.org/10.1021/jacs.8b13899

Internet

https://www.ncbi.nlm.nih.gov/pmc/articles/PMC6541325/
https://www.ncbi.nlm.nih.gov/pubmed/30768254
http://dx.doi.org/10.1021/jacs.8b13899

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