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Bio-inspired iron-catalyzed oxidation of alkylarenes enables late-stage oxidation of complex methylarenes to arylaldehydes

It is a long-standing challenge to achieve efficient and highly selective aerobic oxidation of methylarenes to benzaldehydes, owing to overoxidation problem stemming from the oxidizability of benzaldehyde far higher than the toluene under usual aerobic conditions. Herein we report a bio-inspired iro...

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Detalles Bibliográficos
Autores principales: Hu, Penghui, Tan, Mingxi, Cheng, Lu, Zhao, Hongyuan, Feng, Rui, Gu, Wei-Jin, Han, Wei
Formato: Online Artículo Texto
Lenguaje:English
Publicado: Nature Publishing Group UK 2019
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC6546739/
https://www.ncbi.nlm.nih.gov/pubmed/31160563
http://dx.doi.org/10.1038/s41467-019-10414-7