Synthesis and Structural Dynamics of Five-Coordinate Rh(III) and Ir(III) PNP and PONOP Pincer Complexes

[Image: see text] The synthesis and characterization of a homologous series of five-coordinate rhodium(III) and iridium(III) complexes of PNP (2,6-(tBu(2)PCH(2))(2)C(5)H(3)N) and PONOP (2,6-(tBu(2)PO)(2)C(5)H(3)N) pincer ligands are described: [M(PNP)(biph)][BAr(F)(4)] (M = Rh, 1a; Ir, 1b; biph = 2,...

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Detalles Bibliográficos
Autores principales: Hood, Thomas M., Leforestier, Baptiste, Gyton, Matthew R., Chaplin, Adrian B.
Formato: Online Artículo Texto
Lenguaje:English
Publicado: American Chemical Society 2019
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC6549213/
https://www.ncbi.nlm.nih.gov/pubmed/31117634
http://dx.doi.org/10.1021/acs.inorgchem.9b00957

Internet

https://www.ncbi.nlm.nih.gov/pmc/articles/PMC6549213/
https://www.ncbi.nlm.nih.gov/pubmed/31117634
http://dx.doi.org/10.1021/acs.inorgchem.9b00957

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