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Synthesis and Structural Dynamics of Five-Coordinate Rh(III) and Ir(III) PNP and PONOP Pincer Complexes
[Image: see text] The synthesis and characterization of a homologous series of five-coordinate rhodium(III) and iridium(III) complexes of PNP (2,6-(tBu(2)PCH(2))(2)C(5)H(3)N) and PONOP (2,6-(tBu(2)PO)(2)C(5)H(3)N) pincer ligands are described: [M(PNP)(biph)][BAr(F)(4)] (M = Rh, 1a; Ir, 1b; biph = 2,...
| Autores principales: | , , , |
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| Formato: | Online Artículo Texto |
| Lenguaje: | English |
| Publicado: |
American
Chemical Society
2019
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| Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC6549213/ https://www.ncbi.nlm.nih.gov/pubmed/31117634 http://dx.doi.org/10.1021/acs.inorgchem.9b00957 |