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Eley–Rideal model of heterogeneous catalytic carbamate formation based on CO(2)–MEA absorptions with CaCO(3), MgCO(3) and BaCO(3)
The mechanism was proposed of heterogeneous catalytic CO(2) absorptions with primary/secondary amines involving ‘catalytic carbamate formation’. Compared with the non-catalytic ‘Zwitterion mechanism’, this Eley–Rideal model was proposed for CO(2) + RR′NH with MCO(3) (M = Ca, Mg, and Ba) with four el...
Autores principales: | , , , , , , , , |
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Formato: | Online Artículo Texto |
Lenguaje: | English |
Publicado: |
The Royal Society
2019
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Materias: | |
Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC6549977/ https://www.ncbi.nlm.nih.gov/pubmed/31218067 http://dx.doi.org/10.1098/rsos.190311 |